1
Department of Chemistry, College of Sciences, Shiraz University, 71454 Shiraz, Iran
2
Department of Chemistry, Estahban Higher Education Center, Estahban, Iran
10.22126/anc.2021.6699.1029
Abstract
Some monocyclic ß-lactams bearing the amino moiety have been synthesized from b-lactams with a nitro functional group. First of all, the nitro β-lactams (2a-f) were prepared via Staudinger reactions of the corresponding imines with different substituted acetic acids. Then, to have more electron-rich sites which can bind to the electron-deficient silver nanoparticles (AgNPs), they converted to amino β-lactams (3a-f) bearing NH2 group by a reduction process. The cycloadducts were characterized by spectral data, including 1H-NMR, 13C-NMR, IR, mass spectroscopy, elemental analyses, and X-ray crystallography. As the last step, the combination of those amino β-lactams with AgNPs was simply obtained by treatment of them with pre-prepared AgNPs solution. SEM images of β-lactams-AgNPs showed nanoparticles distributed on the surface, and UV–Vis absorption spectra of β-lactams-AgNPs displayed a broad peak in the range of 400-550 nm. These observations confirmed the presence of AgNPs on the surface.
Heiran, R., & Jarrahpour, A. (2021). Decoration of monocyclic β-lactams with silver nanoparticles. Advances in Nanochemistry, 3(1), 34-39. doi: 10.22126/anc.2021.6699.1029
MLA
Roghayeh Heiran; Aliasghar Jarrahpour. "Decoration of monocyclic β-lactams with silver nanoparticles". Advances in Nanochemistry, 3, 1, 2021, 34-39. doi: 10.22126/anc.2021.6699.1029
HARVARD
Heiran, R., Jarrahpour, A. (2021). 'Decoration of monocyclic β-lactams with silver nanoparticles', Advances in Nanochemistry, 3(1), pp. 34-39. doi: 10.22126/anc.2021.6699.1029
VANCOUVER
Heiran, R., Jarrahpour, A. Decoration of monocyclic β-lactams with silver nanoparticles. Advances in Nanochemistry, 2021; 3(1): 34-39. doi: 10.22126/anc.2021.6699.1029
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